Product ID:DETALINE IN-HOLE DELAY DETONATORS:DH-1 (ALL
MSDS Date:11/03/1985
FSC:1375
NIIN:00N034491
MSDS Number: BPWGY

E I DU PONT DE NEMOURS & CO INC

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515;302-774-3120

Preparer: PRODUCT MGR, EP, F & FP

Cage: B0589

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

LEAD AZIDE

CAS: 13424-46-9

RTECS: OF8650000

OSHA PEL 0.05 MG/M3 (PB)

ACGIH TLV: 0.15 MG/M3 (PB)

LEAD TETROXIDE; (RED LEAD OXIDE)

CAS: 1314-41-6

RTECS: OG5425000

OSHA PEL 0.05 MG/M3 (PB)

ACGIH TLV: 0.15 MG/M3 (PB)

SILICON

CAS: 7440-21-3

RTECS: VW0400000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

BORON

CAS: 7440-42-8

RTECS: ED7350000

OSHA PEL 10 MG/M3 (AS OXIDE)

ACGIH TLV: 10 MG/M3 (AS OXIDE)

LEAD (SARA III)

CAS: 7439-92-1

RTECS: OF7525000

OSHA PEL 0.05 MG/M3

ACGIH TLV: 0.15 MG/M3 DUST

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

SUPPLIED W/EACH PRODUCT SHIPMENT.

RTECS: 9999999ZZ

PENTAERYTHRITOL, TETRANITRATE

CAS: 78-11-5

RTECS: RZ2620000

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:DOES NOT PRESENT HLTH HAZ IN NORM
HNDLG & USE. HOWEVER, PRODS ARE CLASS C EXPLOS & DETONATION MAY
CAUSE SEV PHYSICAL INJURY, INCL DEATH. OVEREXP TO LEAD MAY CAUSE
ADVERSE EFTS TO BLOOD FORMING, NERV, URINARY & REPRO SYS, INCL
EMBRYOTOX EFTS. SYMPS MAY INCL LOSS OF APPETITE, ANEMIA, DISTURB OF
SLEEP & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:LEAD:GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:FATG. FOR ADDNL INFO SEE OSHA LEAD STD
29CFR1910.1025. NO*X GEN ARE SKIN, EYE & RESP SYS IRRITS. SYSTEMIC
TOX EFTS RESULTING FROM OXIDATION OF LUNG TISS INCL EMPHYSEMA,
BRONCH & BRONCHOPNUEM. ACUTE EXPOS CAN LEAD TO DEATH FROM
ASPHYXIA/PULM EDEMA. IN ANIMALS, NO*X CAUSED METHEMOGLOBINEMIA, WAS
NOT (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREF
MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE O*2. CALL MD. INGEST:CALL
MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINI
MUM OF 15 MINUTES, SEEK ASSISTANCE FROMMD . SKIN:FLUSH W/COPIOUS
AMOUNTS OF WATER. CALL MD . NOTE:GET MED ATTN IMMED IF DETONATION
CAUSES PHYSICAL INJURY.

Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DO NOT FIGHT FIRE. ISOLATE AREA. EVACUATE
PERSONNEL TO SAFE AREA. GUARD AGAINST INTRUDERS.
Unusual Fire/Explosion Hazard:DETONATES WHEN EXPOSED TO HEAT/FLAME.
CLASS C EXPLO (DOT). HAZ GASES PRDCD IN FIRE ARE LEAD FUMES & NO*X,
CO*X & OXIDES OF SILICON & BORON. DETONATES W/(SUPDAT)

Spill Release Procedures:REVIEW FIRE & EXPLO HAZS & SFTY PRECS. USE
APPROP PERSONAL PROT EQUIP. CONTROL ACCESS TO AREA & REMOVE SOURCES
OF FRICITION, IMPACT, HEAT, LOW LEVEL ELEC CURRENT,
ELECTROSTATIC/RF ENERGY. REFER TO MFR 'S "DO'S & DON'TS"
INSTRUCTIONS & WARNINGS (ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATHING FUMES FROM DETONATION.
Other Precautions:REFER TO MFR'S "DO'S & DON'TS" INSTRUCTIONS &
WARNINGS SUPPLIED W/EACH PRODUCT SHIPMENT. OCCUP EXPOSURE TO LEAD
IS REGULATED BY SECTION 1910, 29 CFR 1025.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:COTTONS SOCKS & CONDUCTIVE SOLED SHOES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:DELAY PERIODS). EXPLO HAZ:FRICTION, HEAT,
IMPACT. EFTS OF OVEREXP:CARCIN, BUT CAUSED EMBRYOTOX & REPRO EFTS.
NOTE:LEAD (7439-92-1) APPEARS ON NAVY LIST OF OCCUP REPRO HAZS. SE
EK CONSULTATION FROM APPROP HLTH PROFS CONCERNING LATEST HAZ LIST
INFO & SAFE HNDLG & EXPOS RECOMS .

HCC:E1
Appearance and Odor:ALUMINUM SHELL

Stability Indicator/Materials to Avoid:NO
INCOMPATIBLE W/ACIDS, ALKALIES, OXIDANTS.
Stability Condition to Avoid:DETONATES W/FRICTION, HEAT, IMPACT.
Hazardous Decomposition Products:DETONATION PRODUCES SHRAPNEL, LEAD
FUMES & CO*X, NO*X, OXIDES OF SILICON & BORON.

Waste Disposal Methods:CONSULT EXPLOSIVES MFR FOR RECOM METHODS OF
DESTROYING EXPLOS MATLS. COMPLY W/APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS UNDER AUTHORITY OF RCRA (40 CFR 260-271).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.